Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) — Copper Grade Specification, Properties & Equivalents
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) is a high-conductivity copper alloy revered in India for its excellent brazing and welding characteristics, coupled with good corrosion resistance. Unlike OFHC copper, the phosphorus content in DHP copper acts as a deoxidizer dur
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) is a high-conductivity copper alloy revered in India for its excellent brazing and welding characteristics, coupled with good corrosion resistance. Unlike OFHC copper, the phosphorus content in DHP copper acts as a deoxidizer during melting, ensuring a cleaner product and preventing hydrogen embrittlement during high-temperature processing like welding or brazing. This makes Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) the material of choice for critical applications in the HVAC industry, including refrigeration tubing and air conditioning lines, as well as in plumbing systems for potable water and potable water distribution. Foundries and specialized component manufacturers across India, particularly in the industrial belts of Pune, Chennai, and Gujarat, rely on Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) for heat exchangers and intricate plumbing fittings where integrity and long-term performance are paramount. Its reliable weldability and resistance to oxidation at elevated temperatures solidify its position as a key copper grade for demanding engineering tasks.
Chemical Composition of Deoxidized High Phosphorus (DHP / Cu-DHP / C12200)
DHP Copper (C12200) Chemical Composition
| Element | Min (%) | Max (%) |
| Copper (Cu) | 99.0 | - |
| Phosphorus (P) | 0.015 | 0.040 |
| Iron (Fe) | - | 0.05 |
| Total other elements | - | 0.5 |
Mechanical Properties of Deoxidized High Phosphorus (DHP / Cu-DHP / C12200)
DHP Copper (C12200) Mechanical Properties
| Property | Value (Min) | Unit |
| Tensile Strength (UTS) | 310 | MPa |
| Yield Strength (0.5% ext) | 240 | MPa |
| Elongation at Break | 25 | % |
| Hardness (Rockwell B) | 55-75 | HRB |
| Density | 8.94 | g/cm³ |
| Modulus of Elasticity | 117 | GPa |
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) Copper Available Forms in India
| Shape | Typical Sizes | Standard Length |
| Tubes/Pipes | 1/4" to 4" OD; 0.020" to 0.120" Wall | Up to 20 meters |
| Rod/Bar | 5mm to 50mm Diameter | Up to 3 meters |
| Sheet/Plate | 0.5mm to 10mm Thickness | Custom |
| Wire | 0.1mm to 5mm Diameter | Coils |
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) Copper: Real-world Applications
- HVACR: Seamless tubing for refrigeration and air conditioning systems in India.
- Plumbing: Potable water pipes, hot water lines, and distribution networks.
- Heat Exchangers: Components requiring excellent thermal conductivity and corrosion resistance.
- Electrical Connectors: Where high-temperature soldering or brazing is required.
- Automotive: Fuel and brake lines demanding robust joining methods.
- Industrial Piping: For conveying various fluids and gases where brazing is preferred.
- Fire Sprinkler Systems: Corrosion-resistant tubing for safety applications.
- Radiators: Efficient heat transfer components in automotive and industrial use.
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) Copper: Machinability & Weldability
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper offers good machinability, rating around 80% that of Free Machining Brass (C36000). Its higher phosphorus content, while beneficial for deoxidation, slightly reduces electrical and thermal conductivity compared to pure copper grades like OFHC, but this is often acceptable for its primary applications. Tools made of High-Speed Steel (HSS) or Tungsten Carbide are recommended for machining DHP copper, with speeds typically ranging from 15-30 m/min for turning and 10-20 m/min for drilling, depending on the operation and tool geometry. Generous use of cutting fluids is advised to maintain tool life and achieve a smooth surface finish.
Weldability is a key strength of Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper. It exhibits excellent weldability using TIG (GTAW) and MIG (GMAW) processes, often with filler metals like Cu-P alloys or silicon bronze. The phosphorus content effectively prevents the formation of copper oxides during welding, thereby avoiding porosity and ensuring strong, ductile joints. Oxy-acetylene welding is also possible, but care must be taken to minimize overheating. Due to its low melting point and good ductility, post-weld heat treatment is typically not required for Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper in most plumbing and HVAC applications, though stress-relieving anneals at around 300-400°C can be performed if necessary for specific service conditions.
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) Copper: Heat Treatment & Processing
Heat treatment of Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper is primarily focused on stress relief or annealing to restore ductility after cold working. Annealing temperatures typically range from 500°C to 750°C, depending on the desired grain size and level of softening. For stress relieving, lower temperatures around 250°C to 400°C for 30-60 minutes are sufficient to reduce internal stresses introduced during fabrication, preventing season cracking without significant loss of strength. Complete recrystallization and softening occur above 500°C.
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper cannot be hardened by heat treatment (i.e., by quenching and tempering) as it does not form martensitic structures. Its mechanical properties are primarily enhanced through cold working. Normalizing is not applicable to copper alloys. The critical aspect of processing Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper is ensuring a protective atmosphere or avoiding excessive temperatures during high-temperature brazing or welding to prevent oxidation and maintain the integrity of the deoxidized structure. Careful control of heating and cooling rates during annealing is important to achieve uniform properties throughout the material.
Sourcing Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) Copper in India
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper is widely available from major Indian producers like Hindalco, Vedanta, and Nalco, as well as numerous smaller specialized copper processors and importers. Major stockists and distributors are concentrated in key industrial hubs, with significant availability in Mumbai, Pune, Chennai, and the NCR region. Minimum Order Quantities (MOQs) can vary; for standard tube and pipe sizes, MOQs might range from 100 kg to 500 kg, while for custom forms or smaller quantities, higher MOQs or premium pricing may apply.
The current price band for Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper typically falls between INR 650 to 780 per kg, subject to market fluctuations, purity, form, and order volume. Buyers should always specify their requirements for Material Test Certificates (MTC) as per IS 12456 or relevant ASTM standards (e.g., ASTM B111, ASTM B68), including chemical composition and mechanical properties. Third-party inspection and Positive Material Identification (PMI) are often requested by quality-conscious buyers to ensure compliance with specifications. Procuring Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper with reliable MTCs is crucial for critical applications.
International Equivalents for DHP Copper (C12200)
| Standard | Code |
| IS | Cu-DHP / Alloy C12200 |
| ASTM | C12200 / B111 / B68 / B75 / B134 / B135 |
| EN | CW107C (EN 12450) |
| JIS | C1220P |
| UNS | C12200 |
FAQs about Deoxidized High Phosphorus (DHP / Cu-DHP / C12200)
What makes DHP Copper (C12200) suitable for plumbing in India?
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper is ideal for plumbing applications in India due to its excellent corrosion resistance, particularly against potable water, and its superior brazeability. The phosphorus content prevents oxidation during high-temperature joining processes, ensuring leak-free joints essential for water distribution systems. Its durability and resistance to degradation make Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) a long-lasting choice.
Can DHP Copper (C12200) be used for high-temperature applications?
Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper possesses good performance at elevated temperatures, especially compared to alloys containing elements that could cause issues like embrittlement. While not suited for extremely high-temperature structural applications, its ability to withstand brazing temperatures (often exceeding 500°C) and its good oxidation resistance make Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) excellent for heat exchangers, HVAC tubing, and other systems operating at moderately high temperatures where reliable joints are critical.
What is the difference between DHP Copper (C12200) and OFHC Copper?
The primary difference lies in their phosphorus content and deoxidation process. OFHC (Oxygen-Free High Conductivity) copper has extremely low phosphorus and is deoxidized using methods that leave virtually no residual deoxidizers, maximizing electrical and thermal conductivity. Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper contains a controlled amount of phosphorus (0.015-0.040%) which acts as a deoxidizer, enhancing weldability and brazability but slightly reducing conductivity compared to OFHC. DHP copper is preferred whenjoining integrity is paramount.
How does the phosphorus content affect DHP Copper (C12200) properties?
The phosphorus in Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper serves a crucial role as a deoxidizer during melting, preventing hydrogen embrittlement and ensuring sound welds and braze joints by reacting with copper oxides. While this improves joining capabilities, the residual phosphorus slightly decreases electrical and thermal conductivity compared to pure copper. It also slightly hardens the alloy, contributing to its mechanical strength, but DHP copper cannot be age-hardened like some other copper alloys.
What are common Indian standards for DHP Copper (C12200)?
In India, Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) copper is commonly procured based on specifications aligning with international standards, often referenced alongside IS 12456 which broadly covers copper and copper alloy tubes. For heat exchangers, ASTM B111 is frequently specified. ASTM B68 covers seamless copper tube for refrigeration. While a specific IS standard solely for C12200 might not be as prominent as ASTM, compliance with these ASTM or EN standards, verified by MTCs, is standard practice for Deoxidized High Phosphorus (DHP / Cu-DHP / C12200) procurement in India.
Tags: grade, copper, deoxidized high phosphorus (dhp / cu-dhp / c12200)